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    GE Jun, FENG Yangyang, CHAI Peng, YAN Luke, CHEN Tao. Application of PVDF/TiO2 Electrospun Fiber Membrane in Photodegradation and Oil-Water Separation[J]. Journal of Functional Polymers, 2021, 34(5): 483-489. doi: 10.14133/j.cnki.1008-9357.20210112001
    Citation: GE Jun, FENG Yangyang, CHAI Peng, YAN Luke, CHEN Tao. Application of PVDF/TiO2 Electrospun Fiber Membrane in Photodegradation and Oil-Water Separation[J]. Journal of Functional Polymers, 2021, 34(5): 483-489. doi: 10.14133/j.cnki.1008-9357.20210112001

    Application of PVDF/TiO2 Electrospun Fiber Membrane in Photodegradation and Oil-Water Separation

    • Polyvinylidene fluoride (PVDF) and tetrabutyl titanate (TBOT) are dissolved in a mixed solvent of N, N'-dimethylformamide (DMF) and acetone to electrospun into a fiber membrane. Then, TBOT contained in the electrospun fiber membrane was reduced to titanium dioxide (TiO2) by a one-step hydrothermal method at 150 °C. The PVDF fiber membrane material with TiO2 grown in situ on the surface and inside of the fiber was obtained. The morphology and structure of TiO2 grown on PVDF fibers in situ were determined by scanning electron microscopy (SEM), thermal gravity (TG), X-ray diffractometer (XRD) and Fourier infrared absorption spectroscopy (FT-IR). Then, the degradation effect of the composite film on the three organic dyes (rhodamine B, methyl orange and methylene blue) was tested by UV-visible spectroscopy. Finally, the gravity-driven method was used to separate the oil-water mixture, and the contact angle of the composite membrane to water and oil was tested to explore the oil-water separation effect of the composite membrane. Results show that the composite membrane has a good degradation effect on organic dyes such as rhodamine B, methyl orange, methylene blue. The composite membrane also has good lipophilic and hydrophobic properties. It is separated by a mixture of carbon tetrachloride and water. The composite membrane can effectively realize oil-water separation, and the oil-water separation efficiency can be as high as 98.2%.
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