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    XIA Jun, YUAN Qiaolong, LI Chuan, WANG Xiaolei, HUANG Farong. Preparation and Proformance of Propargyl Phenyl Ether-Containing Phosphoramide Modified Cyanate Esters[J]. Journal of Functional Polymers, 2021, 34(3): 293-300. doi: 10.14133/j.cnki.1008-9357.20201216001
    Citation: XIA Jun, YUAN Qiaolong, LI Chuan, WANG Xiaolei, HUANG Farong. Preparation and Proformance of Propargyl Phenyl Ether-Containing Phosphoramide Modified Cyanate Esters[J]. Journal of Functional Polymers, 2021, 34(3): 293-300. doi: 10.14133/j.cnki.1008-9357.20201216001

    Preparation and Proformance of Propargyl Phenyl Ether-Containing Phosphoramide Modified Cyanate Esters

    • N,N’-di(4-propargyloxyphenyl) phosphoramide (DPPPA) was successfully synthesized by nucleophilic substitution of 4-propargyloxy aniline and phenylphosphonyl dichloride. The structure of DPPPA was characterized by nuclear magnetic resonance (NMR) and Fourier transformation infrared (FT-IR) analyses. DPPPA was used to mix with bisphenol A of dicyanate ester (BADCy) and bisphenol E of dicyanate ester (BEDCy) in solution. The DPPPA modified cyanate esters (BADCy/DPPPA and BEDCy/DPPPA) were obtained after the solvent was evaporated under vacuum. The thermal properties, limited oxygen index (LOI) and mechanical properties of the modified cyanate esters were studied. The results show that the residual yield at 800 ℃ in air of the cured BADCy/DPPPA and cured BEDCy/DPPPA increase from 0 to 33% and 26% in comparison with the cured neat cyanate esters, and the LOI of the cured modified cyanate esters reach 39.7% and 35.4%, but the glass transition temperatures of the cured modified cyanate esters decrease by 19 ℃ and 24 ℃, respectively. The flexural and tensile strength of the cured BADCy/DPPPA are 123 MPa and 45 MPa, which are higher than that of the cured BEDCy/DPPPA. The impact strength of the cured BADCy/DPPPA and BEDCy/DPPPA are 11 kJ/m2 and 14 kJ/m2, respectively. The water absorption of the cured neat cyanate esters decreases with blended with DPPPA.
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