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结合静态光散射表征和耗散粒子动力学模拟解析多级纳米线结构

杨文漪 吴芳升 王立权 林嘉平

杨文漪, 吴芳升, 王立权, 等. 结合静态光散射表征和耗散粒子动力学模拟解析多级纳米线结构[J]. 功能高分子学报,2022,35(2):122-129 doi: 10.14133/j.cnki.1008-9357.20210610002
引用本文: 杨文漪, 吴芳升, 王立权, 等. 结合静态光散射表征和耗散粒子动力学模拟解析多级纳米线结构[J]. 功能高分子学报,2022,35(2):122-129 doi: 10.14133/j.cnki.1008-9357.20210610002
YANG Wenyi, WU Fangsheng, WANG Liquan, LIN Jiaping. Structures of Hierarchical Nanowires Analyzed by Static Light Scattering Characterization and Dissipative Particle Dynamics Simulation[J]. Journal of Functional Polymers. doi: 10.14133/j.cnki.1008-9357.20210610002
Citation: YANG Wenyi, WU Fangsheng, WANG Liquan, LIN Jiaping. Structures of Hierarchical Nanowires Analyzed by Static Light Scattering Characterization and Dissipative Particle Dynamics Simulation[J]. Journal of Functional Polymers. doi: 10.14133/j.cnki.1008-9357.20210610002

结合静态光散射表征和耗散粒子动力学模拟解析多级纳米线结构

doi: 10.14133/j.cnki.1008-9357.20210610002
基金项目: 国家自然科学基金(51833003,21774032)
详细信息
    作者简介:

    杨文漪(1996—),女,硕士生,主要研究方向为大分子自组装。E-mail:15216776867@163.com

    通讯作者:

    王立权,E-mail:lq_wang@ecust.edu.cn

    林嘉平,E-mail:jlin@ecust.edu.cn

  • 中图分类号: O63

Structures of Hierarchical Nanowires Analyzed by Static Light Scattering Characterization and Dissipative Particle Dynamics Simulation

  • 摘要: 由聚(γ-苄基-L-谷氨酸酯)-g-聚乙二醇(PBLG-g-PEG)自组装成的初级胶束可以在低温诱导下再次组装,形成一维多级纳米线。通过静态光散射表征和耗散粒子动力学模拟获取了纳米线在溶液中的结构信息,研究并分析了多级纳米线在溶液中的状态,进而探讨了初始混合溶剂和生长时间对纳米线的影响。研究表明:纳米线的形状因子与散射波矢的依赖关系与观测范围密切相关,揭示了不同聚合度纳米线的结构;多级自组装形成的纳米线可以与高分子类比,表现为刚性高分子特征,这与PBLG链的有序排列密切相关。

     

  • 图  1  初级胶束和纳米线的制备示意图

    Figure  1.  Schematic for preparing spindles and nanowires

    图  2  纳米线的DPD模型

    Figure  2.  DPD model of a nanowire

    图  3  (a)初级胶束和(b)纳米线的R/q关系(样品质量浓度为0.004 g/mL,插图为相应的SEM图,标尺为1 μm)

    Figure  3.  Plots of R/ against q for (a) spindles and (b)nanowires (mass concentration of sample is 0.004 g/mL, SEM images are presented in the inset, where the scale bars is 1 μm)

    图  4  纺锤状胶束的R/、由DPD模拟得到的Pq)以及理论椭球形状模型的Pq)分别与q的依赖关系

    Figure  4.  Plots of R/ as a function of the scatter vector q for the solution of spindle-like micelles; Pq) as a function of the scatter vector q for the solution of ellipsoids from DPD and theory method (The lines are fitting lines)

    图  5  由DPD模拟得到的不同聚合度纳米线的(a)Pq)与q的关系和(b)双对数坐标系下R/q的关系(其中蓝点为实验数据)

    Figure  5.  (a) Plots of Pq) as a function of scatter vector q and (b) log-log plots for R/ as a function of scatter vector q for the nanowires with various polymerization degrees (where the blue dots are experimental data)

    图  6  (a)不同THF-DMF溶剂条件下形成纳米线的SLS图像;(b)DPD模拟得到的不同长径比胶束的Pq)与q关系图

    Figure  6.  (a)SLS profiles of nanowires prepared from various THF-DMF solvents; (b)Pq) as a function of q for spindles with vaiours ε from DPD simulation

    图  7  纳米线随时间变化的SLS图像

    Figure  7.  SLS profiles of nanowires obtained at various growth time

    Mn(PBLG): a—1.2×104; b—1.7×104

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出版历程
  • 收稿日期:  2021-06-10
  • 网络出版日期:  2021-08-23

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