含金鸡钠碱的光活性聚合物:2.含辛可宁的两亲单体及其两亲聚合物
Optically Active Polymers with Cinchona Alkaloids 2. Cinchonine-containing amphiphilic monomers and polymers
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摘要: 通过两亲单体2-丙烯酰胺基烷磺酸与辛可宁成盐后再聚合,或AMCnS聚合成梳型两亲聚合物后再生CN成盐,可获得含辛可宁的两亲聚合物。AMCnS-CN盐及其相应的两亲聚合物具有比CN好得多的溶解性,易溶于氯仿、THF、乙醇、DMF和DMS等极性不同的溶剂。AMCsS-CN盐好得多的溶解性,易溶于氯仿、THF、乙醇、DMF和DMSO等极性不同的溶剂。AMCnS-CN盐在乙醇/氯仿(V/V=1/2)中比旋Abstract: Cinchonine-containing amphiphilic polymers may be obtained either by salification of 2-acrylamidoalkanesulfonic acid(AMC nS) with cinchonine (CN)followed by polymerization, or by polymerizing AMC nS to form the comb-type amphiphilic polymers PAMCnS and