PEG/PED-g-CB化学敏电阻材料的制备及其气敏性能的研究
Preparation of a Chemically Sensitive Resistor Material from Poly(ethylene glycol)/Poly(ethylene glycol)-Grafted Carbon Black and Its Responsibility Against Vapor or Gas
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摘要: 以不同分子量聚乙二醇(PEG)为基体,PEG接枝改性的炉法炭黑(PEG-g-CB)为导电裁流子,采用溶液分散工艺制得一种新鞭的气敏传感器材料。研究了PEG分子量对接枝率及对各种溶剂蒸气的响应性、响应灵敏度的影响;用透射电子显微镜(TEM)和紫外—可见分光光度计考察了两种炭黑粒子分散行为、袁面特性差异及其对响应重复性、稳定性的影响。结果表明,PEG/PEG-g-CB复合材料化学敏电阻体对其良溶剂蒸气如THF、氯仿、丙酮具有很强的响应性,其电阻值可提高到初始电阻的10^4~10^6倍。将这种材料再放入干燥空气中时,电阻又恢复到初始值;而对其不良溶剂如正己烷、甲苯几乎不响应。随PEG分子量的提高,响应灵敏度下降;响应的重复稳定性受炭黑粒子分散行为的影响,从聚合物溶胀行为及逾渗导电理论解释了实验结果。Abstract: A novel vapor or gas sensor material was prepared by dispersing poly(ethylene glycol)-grafted carbon black (PEG-g-CB) into poly(ethylene glycol) with different molecular weight in tetrahydrofuran (THF). The effect of molecular weight on percentage of graf