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    二醋酸纤维素接枝聚乳酸的流变性能

    Rheological Behavior of Cellulose Diacetate-g-PLA Copolymer

    • 摘要: 采用毛细管流变仪对二醋酸纤维素接枝聚乳酸(CDA-g-PLA)的流变行为进行了研究,探讨其熔融纺丝的可纺性。结果表明:共聚物熔体为切力变稀流体,随着接枝链的增长,共聚物熔体的非牛顿指数(n)和表观黏度(ηa)减小,而稠度系数(K)、结构黏度指数(Δη)和黏流活化能(Eη)增加;随着温度的升高,非牛顿指数增大,稠度系数和表观黏度下降,共聚物加工过程黏度偏大,最佳熔融纺丝加工温度应控制在170~180°C。

       

      Abstract: ATo evaluate the meltspinning spinnability of cellulose diacetategraftpoly(lactic acid) copolymer(CDA-g-PLA), the rheological behaviors of CDAgPLA were investigated by means of rheograph 25 rheometer. Results showed that CDAgPLA was a typical pseudo plastic fluid that exhibiting shear thinning phenomena. The nonNewtonian index (n), apparent viscosity(ηa) decreased, but the viscous coefficient(K), structure viscosity index(Δη), viscous activation energy (Eη) of the CDAgPLA melts increased with the increasing of the lactyl sidechains of CDAgPLA. The nonNewtonian index increased, but the viscous coefficient and apparent viscosity decreased with the increasing of the temperature. The best meltspinning processing temperature for CDAgPLA copolymer should be controlled in 170-180°C.

       

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