过氧化物酶催化酚聚合的研究

Studies on the Polymerization of Phenols Catalyzed by Peroxidase in Nonaqueous Media

摘要: 研究过氧化物酶在非水介质中催化酚类化合物的聚合。探讨了有机溶剂的浓度，溶剂极性，体系ＰＨ值、酶浓度等因素对聚酚分子量的影响；分析了聚酚的链结构。结果表明，酚分子之间通过酚羟基的邻位或对位相互连结。形成了分子链上带有酚羟基的聚酚树脂；通过调节聚合参数，可以改变聚酚的分子量。

Abstract: n this paper, the enzymatic polymerizations of z-naphthol and p-phenylphenol in aqueous-organic mixture have been examined. The effects of the polymerization conditions, such as organic solvent concentrations, solvent dielectric constants. pH values of th