具有高分子空穴传输性能的含三芳胺侧链接枝聚苯乙烯的合成与表征

Synthesis and Characterization of Polystyrene Grafting Triarylamines with Hole Transport Performance Property

摘要: 三芳胺类聚合物作为空穴传输材料具有广泛的应用前景。设计、合成了一种新的三芳胺衍生物单体 4 -乙烯基苄氧基亚甲基三苯胺 ,通过NMR、IR及MS等手段对其结构进行了表征。用AIBN引发新单体进行自由基聚合反应 ,得到了侧链带三苯胺基团的高分子空穴传输聚合物 ,该聚合物具有较高玻璃化转变温度及高热稳定性。

Abstract: Polymers containing triarylamine as hole transport material will be widely used in the future. In this study, a new monomer of triarylamine derivative, 4 (vinylbenzyloxymethylene)tripheny lamine was synthesized, and characterized by NMR, IR, MS. The mo