富勒烯化聚环氧丙基咔唑的合成与表征

Preparation and Characterization of Fullerenated Poly(epoxy propyl carbazole)

摘要: 通过Ｆｒｉｅｄｅｌ－Ｃｒｒａｆｔｓ反应制备了富勒烯化的聚环氧丙基咔唑，聚合物中Ｃ６０的含量最高可达７．６ｗｔ％。通过凝胶渗透色谱法测定了聚合物分子量，并采用＾上Ｈ和＾１３Ｃ－ＮＭＲ，ＩＲ，热分析及光谱等手段对其结构进行了分析与表征。

Abstract: The fullerenated PEPCPoly(epoxy propyl carbazole) was synthesized by Friedel-Crafts type reactions. Molecular weights of the polymers were determined by gel permeation chromatography. Structures of the polymers were analyzed and characterized by use of