聚甲基丙烯酸三苯基锡酯的配位形式及其对凝聚态和溶解性能的影响

Dependance of the Structure and the Property of Polytriphenyltin Methacrylate on Its Coordinative Forms

摘要: 用不同沉淀剂沉淀出来的聚甲基丙烯酸三苯基锡酯(PTPTM)具有不同的溶解性能。本文用FTIR研究了PTPTM中存在的各种不同的配位形式及其对PTPTM的凝聚态结构和溶解性能的影响。讨论了PTPTM可能存在的三种凝聚态以及在不同条件下的相互转化。

Abstract: Polytriphenyltin methacrylate (PTPTM) behaved differently in dissolvability when it was precipitated in different precipitants, in particular the coordinative crosslinking would take place when PTPTM was precipitated in methanol. It was considered that th