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    基于反应型线性聚磷腈的双马来酰亚胺树脂阻燃和增韧一体化设计

    Integrated Design of Flame Retardancy and Toughening for Bismaleimide Resins Based on Reactive Linear Polyphosphazene

    • 摘要: 针对双马来酰亚胺树脂(BMI)的阻燃与增韧难协同的问题,本研究设计并合成了含马来酰亚胺侧链的线性聚磷腈(PHMP),并将其引入二烯丙基双酚A/4,4'-双马来酰亚胺二苯甲烷(DBA/BDM)体系。PHMP凭借活性侧基参与树脂固化,结合磷氮阻燃主链,实现了BMI的阻燃与增韧协同改性。仅需添加质量分数4%的PHMP,改性树脂的冲击强度提升124.6%的同时,总热释放与烟释放分别降低41.0%和32.1%,极限氧指数达35.5%,并通过UL-94 V-0级。该研究为BMI多功能集成改性提供了新思路。

       

      Abstract: A maleimide-functional linear polyphosphazene (PHMP) was developed to address the challenge of achieving simultaneous toughening and flame retardancy in bismaleimide (BMI) resins. PHMP was introduced into the diallyl bisphenol A / 4,4'-bismaleimidodiphenylmethane (DBA/BDM) resin system to achieve integrated regulation of flame retardancy, smoke suppression, and toughening. Owing to its reactive side groups and phosphorus-nitrogen backbone, PHMP can participate in the curing network while imparting flame-retardant functionality. The results show that PHMP significantly improves the mechanical and fire-safety performance of the resin while maintaining good heat resistance. With the addition of only 4% (mass fraction) PHMP, the impact strength of the modified resin increases by 124.6%, while the total heat release and total smoke production decrease by 41.0% and 32.1%, respectively. Moreover, the limiting oxygen index reaches 35.5% and the material achieves a UL-94 V-0 rating. This study provides a new strategy for the multi-functional integrated modification of BMI resins.

       

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