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    聚丙烯酰胺/聚乙烯醇基导电水凝胶的制备及传感应用

    Preparation and Sensing Application of Polyacrylamide/Polyvinyl Alcohol-Based Conductive Hydrogels

    • 摘要: 通过共聚和冻融循环将丙烯酰胺(AM)、磺基甜菜碱甲基丙烯酸酯(SBMA)和聚乙烯醇(PVA)制备成双网络水凝胶,并将其浸泡于柠檬酸钠(Na3Cit)的甘油/水溶液中,从而形成P(AM-co-SBMA)/PVA-Cit离子导电水凝胶。用扫描电镜、傅里叶红外光谱对水凝胶的组成和微观结构进行表征,用万能试验机测试水凝胶的拉伸和黏附性能,用数字万用表与拉伸机结合对水凝胶进行应变传感应用。该离子导电水凝胶具有优异的力学性能、黏附性、保水性、导电性,其最大伸长率和离子电导率分别为940%和1.83 S/m,抗拉强度为1.75 MPa,黏附强度为27 kPa。作为柔性应变传感器的水凝胶具有优异的拉伸应变灵敏度(应变灵敏因子(GF)为3.021)、快速响应和稳定的电信号输出。

       

      Abstract: A dual-network hydrogel was prepared by copolymerization and freeze-thaw cycles using acrylamide (AM), Sulfobetaine methacrylate (SBMA), and polyvinyl alcohol (PVA). The hydrogel was immersed in an inorganic salt solution (glycerol/water) containing Na3Cit to form P(AM-co-SBMA)/PVA-Cit ionically conductive hydrogels. The composition and structure of the hydrogels were analyzed by scanning electron microscopy and Fourier transform infrared spectroscopy. The mechanical properties and adhesion performance were tested using a universal testing machine, and the strain-sensing capability was evaluated through simultaneous electrical resistance measurement during tensile stretching. It exhibits excellent mechanical properties, adhesion, water retention, and conductivity. The maximum elongation and ionic conductivity of this ionically conductive hydrogel are 940% and 1.83 S/m, respectively, with a tensile strength of 1.75 MPa and an adhesion strength of 27 kPa. As a flexible strain sensor, the hydrogel demonstrates excellent tensile strain sensitivity (GF = 3.021), rapid response, and stable electrical signal output.

       

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