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    聚丙烯酰胺/聚乙烯醇基导电水凝胶的制备及传感应用

    Preparation and Sensing Application of Polyacrylamide/Polyvinyl Alcohol-Based Conductive Hydrogels

    • 摘要: 通过共聚与冻融循环将丙烯酰胺(AM)、磺基甜菜碱甲基丙烯酸酯(SBMA)和聚乙烯醇(PVA)制备成双网络水凝胶,并将其浸泡于柠檬酸钠(Na3Cit)的甘油/水溶液中,从而形成P(AM-co-SBMA)/PVA-Cit离子导电水凝胶。用扫描电镜、傅里叶变换红外光谱对水凝胶的组成及微观结构进行表征,用万能试验机测试水凝胶的拉伸与黏附性能,通过数字万用表与拉伸机结合对水凝胶进行应变传感应用测试。结果表明,该离子导电水凝胶具有优异的力学性能、黏附性、保水性、导电性,其最大伸长率与离子电导率分别为940%与1.83 S/m,抗拉强度为1.75 MPa,黏附强度为27 kPa。作为柔性应变传感器的水凝胶具有优异的拉伸应变灵敏度(应变灵敏因子(GF)为3.021)、快速的响应和稳定的电信号输出。

       

      Abstract: A dual-network hydrogel was prepared by copolymerization and freeze-thaw cycles using acrylamide (AM), sulfobetaine methacrylate (SBMA), and polyvinyl alcohol (PVA). The hydrogel was immersed in an inorganic salt solution (glycerol/water) containing sodium citrate (Na3Cit) to form the P(AM-co-SBMA)/PVA-Cit ionically conductive hydrogel. The composition and structure of the hydrogel were characterized using scanning electron microscopy and Fourier transform infrared spectroscopy. Mechanical properties and adhesion performance were tested using a universal testing machine, and the strain-sensing capability was evaluated by simultaneous electrical resistance measurement during tensile stretching. The hydrogel exhibits excellent mechanical properties, adhesive properties, water retention, and conductivity. Its maximum elongation and ionic conductivity reach 940% and 1.83 S/m, respectively, with a tensile strength of 1.75 MPa and an adhesion strength of 27 kPa. As a flexible strain sensor, the hydrogel demonstrates excellent tensile strain sensitivity (gauge factor (GF): 3.021), rapid response, and stable electrical signal output.

       

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