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    相变微胶囊基Lyocell纤维的制备及性能

    Preparation and Properties of Phase Change Microcapsule-Based Lyocell Fibers

    • 摘要: 将相变微胶囊(PCM)与纤维素纺丝液共混,采用干喷湿纺技术制备出一系列不同PCM添加量(质量分数)的相变Lyocell纤维,采用场发射扫描电镜、红外光谱仪、纤维强度仪、差示扫描量热仪等分析了PCM添加量对纤维性能的影响。结果表明:PCM均匀分散于纤维中;随着PCM添加量的增加,纤维表面越粗糙,纤维的断裂强度下降、断裂伸长提高,纤维焓值增加,并且有较好的热循环稳定性。当PCM的添加量为30%时,纤维断裂强度为2.98 cN/dtex,熔融焓为30.1 J/g,结晶焓为31.9 J/g。染色结果表明:与不含PCM的纤维相比,添加量为30%的纤维吸色率与固色率均出现下降,但仍具有非常好的染色性能。

       

      Abstract: A series of phase change Lyocell fibers with different phase change microcapsule (PCM) addition amounts (mass fractions) were prepared by blending PCMs with cellulose spinning liquid via dry-jet wet-spinning technology. The influence of the PCM addition amount on properties of the fibers was analyzed using field-emission scanning electron microscopy, infrared spectrometry, fiber strength meter, and differential scanning calorimetry. The results showed that PCM was uniformly dispersed in the fibers. With the increase of PCM addition amount, the fiber surface became rougher, the fiber breaking strength decreased, and the breaking elongation, enthalpy, and thermal cycling stability all increased. At a PCM addition amount of 30%, the fiber exhibited a breaking strength of 2.98 cN/dtex, a melting enthalpy of 30.1 J/g, and a crystallization enthalpy of 31.9 J/g. Dyeing tests revealed that, compared to the pure Lyocell fiber (without PCM), the fiber with 30% PCM addition amount exhibited lower dye uptake and fixation rates. Nevertheless, it still had excellent dyeing performance.

       

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