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    聚乳酸纤维对热塑性淀粉塑料性能的影响

    Effect of Polylactic Acid Fiber on the Properties of Thermoplastic Starch Plastics

    • 摘要: 为增强热塑性淀粉(TPS)的力学及耐水性能,通过挤出注塑工艺制备了聚乳酸纤维(PLAF)增强的TPS复合材料(PLAF/TPS)。采用万能试验机、扫描电镜(SEM)、接触角测定仪、热重分析仪(TG)和转矩流变仪对PLAF/TPS复合材料的性能进行了表征。结果表明:适量的PLAF能够较好地分散在TPS基体中,并与淀粉分子形成氢键,从而显著增强TPS的力学及耐水性能。当PLAF的添加量(质量分数)为1.0%时,复合材料的拉伸强度及冲击强度从纯TPS的1.98 MPa、33.45 kJ/m2提高到6.79 MPa、43.71 kJ/m2,断裂伸长率有所下降;PLAF的添加能使复合材料表面的接触角由纯TPS的46.3°增加到最大88.5°,耐水性能显著改善;PLAF使TPS的热稳定性略有提高;PLAF/TPS复合材料的加工性能随着PLAF添加量的增加而变差,当PLAF添加量为1.0%时,PLAF/TPS适宜加工成型。

       

      Abstract: Considering the environmental pollution and the lack of oil resources, degradable polymers have been widely concerned by researchers in recent years. As one of the research focuses, the strengthening of mechanical properties and water resistance of thermoplastic starch (TPS) have been studied. In order to enhance the mechanical and water resistance properties of TPS, the polylactic acid fiber (PLAF) reinforced TPS plastics (PLAF/TPS) were prepared by extrusion and injection molding. The effects of mass fraction of PLAF (0.5%~2.5%) on mechanical, section morphology, water resistance, thermal stability and torque rheological properties of PLAF/TPS were studied in detail. Results show that PLAF with the appropriate mass fraction can be dispersed uniformly in the TPS matrix and form hydrogen bonds with starch molecules, which can significantly enhance the mechanical and water resistance properties of TPS. Compared with 1.98 MPa and 33.45 kJ/m2 of the unreinforced TPS, the maximum values of tensile strength and impact strength of 1.0% PLAF/TPs can reach 6.79 MPa and 43.71 kJ/m2 respectively, which due to the uniformly dispersed PLA fibers in the TPS matrix and the interaction between PLA fibers and starch macromolecules. In the meantime, the elongation at break decreases due to the increasing brittleness of the PLAF/TPS, and the surface contact angle is enhanced from 46.3° to 88.5°, proving that the water resistance is improved effectively because the hydrophobic PLA fibers disperse uniformly in TPS matrix. The thermal stability of PLAF/TPS is also improved slightly due to small amount of the PLA fibers dispersing in TPS. The processing performance of PLAF/TPS composite is poor with the increasing PLAFs, which is due to the entanglement of PLA fibers and the interaction between PLA fibers and starch macromolecules. The 1.0%PLAF/TPS is easier to be processed compared with other PLAF/TPS composites with higher PLAF content.

       

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