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    磺化明胶水凝胶的制备及其电场响应性能

    Synthesis and Electric-Field Response Property of Sulfonated Gelatin Hydrogels

    • 摘要: 采用明胶为原料,以甲基丙烯酸缩水甘油酯和亚硫酸氢钠为改性剂,在明胶分子链上引入极性基团磺酸基,制得新型磺化明胶水凝胶。采用红外光谱(FT-IR)、X射线光电子能谱(XPS)和扫描电镜(SEM)对其组成和结构进行了表征。通过动态黏弹谱仪(DMA)测定水凝胶的储能模量,探讨不同外加电场作用下该水凝胶的电场响应性能。随着明胶水凝胶中S元素的原子百分比的增大,在外加电场下,胶体的电场响应能力增强。当外加电场为1.6 kV/mm、明胶水凝胶中S的原子百分比为1.59%时,水凝胶对电场作用的响应最明显,储能模量的增加率为31.86%。

       

      Abstract: The sulfonated gelatin hydrogels were obtained using gelatin as material and glycidyl methacrylate and NaHSO3 as modifier.Then,sulfonic acid groups were covalently immobilized onto gelatin.The chemical component and structure of the hydrogels were verified by Fourier Transform Infrared Spectra (FT-IR),X-ray Photoelectron Spectroscopy (XPS) and Scanning Electron Microstructures (SEM).The dynamic viscoelastic spectrometer was used to investigate the storage modulus.The electric-field responses of the hydrogels under different external electric fields were disscussed.Results showed that the electric-field response was enhanced under an external applied electric-field with the increasing percentage of S atom in sulfonated-gelatin hydrogel.When the applied electric-field was 1.6 kV/mm and the percentage of S atom in sulfonated gelatin hydrogels was 1.59%,the hydrogels had the strongest response and the storage modulus increment sensitivity was up to 31.86%.

       

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