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    槲皮素磁性分子印记聚合物的制备及其吸附性能

    Preparation and Adsorption Property of Quercetin Magnetic Molecularly Imprinted Polymers

    • 摘要: 以槲皮素(Qu)为模板分子、N-乙烯基吡咯烷酮(NVP)和丙烯酸(AA)为功能单体、N,N'-亚甲基双丙烯酰胺(MBA)为交联剂、H2O2-Vc为引发剂、KH570修饰的Fe3O4纳米颗粒为磁性载体,借助表面分子印迹技术制备了能够对Qu进行特异性识别的槲皮素磁性分子印迹聚合物(Qu-MMIPs)。利用X射线衍射仪(XRD)、透射电子显微镜(TEM)、傅里叶变换红外光谱仪(FT-IR)、振动样品磁强计(VSM)和紫外-可见分光光度计(UV-Vis)对样品进行了结构和性能表征。结果表明:Fe3O4磁性载体表面已成功包覆了分子印迹聚合物。与化学组成相同的磁性非印迹聚合物(Qu-MNIPs)相比,Qu-MMIPs对Qu有较高的吸附选择性。静态吸附平衡实验和Scatchard分析结果表明,Qu-MMIPs中存在两类不同的结合位点,平衡解离常数分别为1.646×10-6mol/L和6.387×10-6mol/L,最大吸附量分别为23.041 mg/g和29.923 mg/g。

       

      Abstract: Quercetin(Qu)magnetic molecularly imprinted polymers(Qu-MMIPs)with the specific recognizing property for Qu,were prepared using Qu as template molecule,acrylamide(AA)and N-vinylpyrrolidone(NVP)as functional monomers,N,N'-methylene bisacrylamide(MBA)as crosslinker,H2O2-Vc as initiator and Fe3O4 nanoparticles(NPs)modified with γ-methacryloxypropyltrimethoxysilane(KH570)as magnetic carrier.The as-synthesized polymers were characterized by X-Ray Diffraction(XRD),Transmission Electron Microscopy(TEM),Fourier Transform Infrared Spectroscopy(FT-IR),Vibrating Sample Magnetometer (VSM)and UV-Visible Spectrophotometer(UV-Vis).Results indicated that the modified Fe3O4 magnetic carriers were coated with molecularly imprinted polymers.In comparison with magnetic molecularly non-imprinted polymers,Qu-MMIPs had better recognition performance for the Qu molecules.Static adsorption test and Scatchard analysis showed that two kinds of binding sites existed in Qu-MMIPs,and the corresponding dissociation constants were 1.646×10-6mol/L and 6.387×10-6mol/L.Furthermore,the maximum adsorption capacities of Qu onto Qu-MMIPs were 23.041 mg/g and 29.923 mg/g,respectively.

       

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