苯乙烯在顺1,4-聚丁二烯上的接枝共聚反应动力学的Monte  Carlo模拟

Monte Carlo Simulation Method of the Kinetics of Graft Polymerization of Styrene on cis-1,4-Polybutadiene

摘要: 用ＭｏｎｔｅＣａｒｌｏ模拟方法对苯乙烯在顺１，４－聚丁二烯上的接枝反应动力学进行了研究。模拟结果表明，对于不同的橡胶浓度，接枝的和均聚的聚苯乙烯的数均聚合度、接枝效率与苯乙烯在顺１，４－聚丁二烯上的接枝共聚反应的动力学的解析解十分吻合，证明本方法能够有效地应用于自由基型接枝共聚合反应体系。

Abstract: In this paper,the kinetics of graft polymerization of styrene on cis-1,4-polybutadiene were studied by means of Monte Carlo simulation method. The results of Monte Carlo simulation ,including the values of the number average degree of polymerization of gr