^13C—NMR研究环氧乙烷—环氧丙烷无规共聚物的序列结构
13 C-NMR Study of the Sequence Structure of Statistical Copolymers of Ethylene Oxide and Propylene Oxide
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摘要: 利用高分辨核磁共振谱仪研究了环氧乙烷-环氧丙烷均聚物和无规共聚物的核磁共振主链碳谱。在对其链结构进行有效归属的基础上,讨论了不同配比聚合物的僚共振主链碳谱特点及其可能的单元链节排列顺序。Abstract: C-NMR spectra of homopolymers and statistical copolymers of ethylene oxide (EO) and propylene oxide (PO) have been studied in CDCl 3 solution. On the basis of assignment of diad and triad sequences,characterizations of the main chain carbon-13 spectra o