聚氧乙烯/聚酚氧共混体系的结晶行为及相容性研究
Miscibmty and Crystallizattion Kinetics of PEO(poly(ethylene oxide)) / PH(poly(hydroxy ether) of bisphenol A)) Blends
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摘要: 对聚氧化乙烯/聚酚氧(PEO/PH)共混体系的研究表明,随共混体系中非晶组份PH含量的增加,Avrami指数n值由2.0~2.3变为1.5~2.0,体系的结晶由盘状生长转化为纤维状生长;成核方式由方式Ⅰ转化为方式Ⅱ.PEO/PH共混体系的平衡熔点随PH含量的增加而降低,相互作用能量密度B=-1.46cal/mol,说明体系是互容的。Abstract: Miscibility and crystallization behavior of solution-cast films of PEO/PH blends have heen investigated by using differential scanning calorimetry and polarizing microscope. As a function of composition and temperature, the values of Avrami exponent are n