含有偶氮染料侧基的聚氨酯(脲)的研究
Study of Polyurethanes(ureas) Pendant with Azo-dye
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摘要: 用扩链法合成了一系列含有偶氮染料的侧基聚氨酯和聚脲。TF-IR、DSC、DMA的研究表明,聚合物有良好的力学性能,样品中软硬段的含量决定材料的物理性能。通过UV的测定,计算出样品均有较高的三阶非线性光学(NLO)系数。Abstract: Polyurethanes(ureas) pendant with different kinds of azo dye were synthesized by using azo dye diols or diamines as chain extender in a two step block copolymerization reaction. The polymers were characterized by FT IR, DSC, DMA, and UV. The samples ex