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    高英, 秦爱文, 李翔, 马博谋, 何春菊. 埃洛石-聚醚砜复合膜的形态结构及性能[J]. 功能高分子学报, 2012, 25(4).
    引用本文: 高英, 秦爱文, 李翔, 马博谋, 何春菊. 埃洛石-聚醚砜复合膜的形态结构及性能[J]. 功能高分子学报, 2012, 25(4).
    GAO Ying, QIN Ai wen, LI Xiang, MA Bo mou, HE Chun ju. Morphology Structure and Properties of Halloysite PES Composite Membranes[J]. Journal of Functional Polymers, 2012, 25(4).
    Citation: GAO Ying, QIN Ai wen, LI Xiang, MA Bo mou, HE Chun ju. Morphology Structure and Properties of Halloysite PES Composite Membranes[J]. Journal of Functional Polymers, 2012, 25(4).

    埃洛石-聚醚砜复合膜的形态结构及性能

    Morphology Structure and Properties of Halloysite PES Composite Membranes

    • 摘要: 通过非溶剂致相分离法成功制备了多孔性埃洛石-聚醚砜复合膜。通过扫描电镜观察了膜的微观结构,并对膜的水通量、截留率、亲水性和力学性能等进行了研究。结果表明:埃洛石的加入使得非对称性膜由海绵状结构转变为大指状孔结构。当凝固浴温度为40 ℃时,复合膜的水通量均比原膜的低。当埃洛石的质量分数为2%时,复合膜的水通量随着凝固浴温度的升高而升高。当埃洛石的质量分数从2%增加到8%时,复合膜的截留率和亲水性随之增加,力学性能随之降低。

       

      Abstract: The halloysite nanotubes polyethersulfone (HNTs-PES) composite membranes were successfully prepared through non solvent induced phase separation (NIPS). The structure of formed membranes was investigated using scanning electron microscopy together with the corresponding performance such as water flux, rejection rate, hydrophilicity and mechanical strength. Results show that the addition of halloysite nanotubes changes the structure of the asymmetric membranes from sponge like structure to finger like structure, and the water flux of composite membranes are all lower than those of raw membrane at coagulation bath temperature 40 ℃. The water flux increases with the increasing of coagulation bath temperature when wHNTs=2%. While the rejection rate and hydrophilicity increase at the expense of reduction of mechanical strength with the increasing of halloysite mass fraction from 2% to 8%.

       

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