聚合物负载的手性催化剂和手性试剂和合成及应用
The Synthesis and Applications of Polymer-Supported Chiral Catalysts and Reagents
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摘要: 近年来,用聚合物负载的手性催化剂和手性试剂完成的不对称合成反应主要集中在潜手性酮的不对称还原反应;烯烃的不对称双羟基化反应;烯烃的不对称环氧化反应;不对称Diels-Alder反应和饱和碳原子上的不对称取代反应。就近十年来聚合物负载手性催化剂和手性试剂的合成及应用进行了讨论。Abstract: The researches in asymmetric reactions catalyzed by polymer-supported chiral catalysts and reagents mainly focus on the asymmetric reduction of ketones, the asymmetric dihydroxylation of olfines, the asymmetric epoxidation of alkenes, the asymmetric diels