含硅芳香二酐的合成及其聚酰亚胺
Synthesis of a Silicon-Containing Aromatic Dianhydride and its Polyimide
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摘要: 从4-溴-l,2-二甲苯出发,经过三步反应合成了双-(3,4-苯二甲酸酐)二甲基硅烷单体,总产率为24.7%;由该单体与4,4′-二氨基二苯醚共聚合,经环化脱水反应得含硅聚酰亚胺,并对该共聚物进行了初步表征。Abstract: Monomer bis(3,4-dicarboxyphenyl)dimethylsilane dianhydride was synthesized from 4-bromo-1,2-dimethyl-benzene and dichlorodimethylsilane through Wurtz coupling reaction , oxidization and cyclization reaction with the overall yield of 24. 7% . And bis(3,4-d