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    林飞云, 冯杰, 黄明达, 钟明强. 基于不锈钢模板热压微模塑构建聚乙烯超疏水表面[J]. 功能高分子学报, 2010, 23(2): 211.
    引用本文: 林飞云, 冯杰, 黄明达, 钟明强. 基于不锈钢模板热压微模塑构建聚乙烯超疏水表面[J]. 功能高分子学报, 2010, 23(2): 211.
    Fabricating Polyethylene Superhydrophobic Surfaces by Thermal Replica-Molding Using Etched Stainless Steel Surfaces as Templates[J]. Journal of Functional Polymers, 2010, 23(2): 211.
    Citation: Fabricating Polyethylene Superhydrophobic Surfaces by Thermal Replica-Molding Using Etched Stainless Steel Surfaces as Templates[J]. Journal of Functional Polymers, 2010, 23(2): 211.

    基于不锈钢模板热压微模塑构建聚乙烯超疏水表面

    Fabricating Polyethylene Superhydrophobic Surfaces by Thermal Replica-Molding Using Etched Stainless Steel Surfaces as Templates

    • 摘要: 采用含FeCl3的蚀刻液对不锈钢表面进行刻蚀,再以此蚀刻面为模板热压低密度聚乙烯(LDPE),冷却剥离得到LDPE微模塑表面。研究结果表明:静、动态接触角均超过150°,滚动角约5°,LDPE表面呈“花菜状”结构,即大“包”上密集分布着微米及亚微米级的小突起。本工艺可望结合工业上生产塑料薄膜的流延技术,实现聚合物超疏水表面的规模化生产。

       

      Abstract: Stainless steel smooth surface was first roughed by etching in FeCl3 containing solution towards working as thermal replicamolding template. Then the polyethylene was thermally pressed onto such etched surfaces. After being cooled to room temperature and stripped off from the templates, the polyethylene replica surfaces were created. Results show that static and dynamic water contact angles are more than 150° and sliding angle is about 5°. Such superhydrophobic surfaces have cauliflower like structure, e.g., cluster of spine like microstructures. This novel process can be combined with flowcasting process, a main technique for manufacturing plastic films, thus will be meaningful in developing new technique for manufacturing plastic superhydrophobic surfaces in a large scale.

       

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