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    陆飞, 宋俊, 程博闻, 梁义. 纤维素-[Amim]Cl浓溶液的稳态流变规律[J]. 功能高分子学报, 2010, 23(2): 149-154.
    引用本文: 陆飞, 宋俊, 程博闻, 梁义. 纤维素-[Amim]Cl浓溶液的稳态流变规律[J]. 功能高分子学报, 2010, 23(2): 149-154.
    Rheological Behavior of Cellulose-[Amim]Cl Concentrated Solvent[J]. Journal of Functional Polymers, 2010, 23(2): 149-154.
    Citation: Rheological Behavior of Cellulose-[Amim]Cl Concentrated Solvent[J]. Journal of Functional Polymers, 2010, 23(2): 149-154.

    纤维素-[Amim]Cl浓溶液的稳态流变规律

    Rheological Behavior of Cellulose-[Amim]Cl Concentrated Solvent

    • 摘要: 对纤维素-氯代1-烯丙基-3-甲基咪唑([Amim]Cl)浓溶液在不同温度下的稳态流变规律进行了研究。测试结果显示:纤维素-[Amim]Cl浓溶液属于假塑性流体。运用Cross和Carreau两种黏度模型对实验数据进行拟合,得到了表观黏度的主曲线,通过Arrhenius方程确定了移位活化能(ΔEa)为91.86~164.97 kJ/mol。与纤维素-氯代1-丁基-3-甲基咪唑([Bmim]Cl)溶液、纤维素-N-甲基吗啉-N-氧化物(NMMO)溶液、熔融聚合物(如聚丙烯、聚乙烯等)的活化能以及流变规律进行了对比。结果表明,纤维素-[Amim]Cl浓溶液的ΔEa较高,温度对体系黏度影响较大。

       

      Abstract: The rheological behavior of cellulose 1-allyl-3-methylimidazolium chloride ([Amim]Cl) concentrated solution was studied by measuring the apparent viscosities at different temperatures. The [Amim]Cl cellulose solution was pesudoplastic fluid. Master curves were generated for apparent viscosity by using Carreau and Cross viscosity models to fit experimental data. From the Arrhenius equation, the activation energies of the shift factors are between 91.86 and 164.97 kJ/mol. Furthermore, activation energies and rheological behavior with those of N-methylmorpholine-N-oxide(NMMO) cellulose solutions and polyethylene, polystyrene and polycarbonate were compared with cellulose-[Amim]Cl solution. The activation energies of cellulose-[Amim]Cl solution are higher than others and temperature has a great effect on solution viscosity.

       

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