超高分子量聚乙烯凝胶/结晶膜中链缠结的Raman研究
Study on the Interface of UHMWPE Gel-Films by Raman Spectroscopy
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摘要: 为获得超高分子量聚乙烯的超高取向性,利用准稀溶液速冷解缠方法可使λm=400,力学性能大幅度提高,但距离链的理论强度还有一定差距,NMR的相结合研究表明其中仍残存一定量的界面层及非晶部分。从缠经链角度来看,其分子链的解缠并不能达到完全。Abstract: The effect of annealing and drawing on the phase structure of ultrahigh molecular weight polyethylene (UHMWPE) gel-films was studied by Raman spectroscopy. Our attention focused mainly on the mass fraction changes of interface phase. The results were also