乙醇酸和DL─乳酸交替共聚物的合成和表征
Synthesis and Characterization of Alternating Copolymer of DL-Lactic Acid and Glycolic Acid
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摘要: 乙醇酸和DL-乳酸交替共聚物具有不同于其无规共聚物的理化性能和生物降解性。以DL-3-甲基-1,4-二烷-2,5-二酮为单体,通过在辛酸亚锡引发下的本体开环聚合,合成了该交替共聚物,并进行了结构表征。Abstract: n alternating copolymer of DL-lactic acid and glycolic acid was synthesized by ring-opening polymerization of DL-3-methyl-1,4-dioxane-2,5-dione upon initiation with an appropriate amount of stannous octoate.The polymer was characterized by 1H-/13C -NMR, D