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    潘才元, 吴承佩, 王寅. 2-甲基-7-亚甲基-1,4,6-三氧螺[4,4]壬烷与丙烯腈、丙烯酸甲酯的共聚合反应及竞聚率的测定[J]. 功能高分子学报, 1992, 5(4).
    引用本文: 潘才元, 吴承佩, 王寅. 2-甲基-7-亚甲基-1,4,6-三氧螺[4,4]壬烷与丙烯腈、丙烯酸甲酯的共聚合反应及竞聚率的测定[J]. 功能高分子学报, 1992, 5(4).
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    Copolymerization of 2-Methyl-7-Methylene-1, 4, 6-Troxaspiro (4,4) Nonane with Acrylonitrile, Methyl Acrylate and Measurement of Monomer Reactivity Ratioes[J]. Journal of Functional Polymers, 1992, 5(4).
    Citation: Copolymerization of 2-Methyl-7-Methylene-1, 4, 6-Troxaspiro (4,4) Nonane with Acrylonitrile, Methyl Acrylate and Measurement of Monomer Reactivity Ratioes[J]. Journal of Functional Polymers, 1992, 5(4).
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    2-甲基-7-亚甲基-1,4,6-三氧螺4,4壬烷与丙烯腈、丙烯酸甲酯的共聚合反应及竞聚率的测定

    Copolymerization of 2-Methyl-7-Methylene-1, 4, 6-Troxaspiro (4,4) Nonane with Acrylonitrile, Methyl Acrylate and Measurement of Monomer Reactivity Ratioes

      摘要
    • 摘要: 用高效液相色谱跟踪2-甲基-7-亚甲基-1,4,6-三氧螺4,4壬烷(MMTN)与丙烯腈(AN),丙烯酸甲酯(MA)的共聚合反应。根据Lowry-Meyer共聚积分方程式,采用插值法进行数据拟合测定单体的竞聚率。对于体系MMTN(M_1)-AN(M_2),r_1=0.048;r_2=0.213;MMTN(M_1)-MA(M_2)r_1=0.025,r_2=0.764。说明两组共聚体系均有较强的交替共聚趋势。

       

      Abstract: The copolymerization of 2--methyl--7--methylene--1,4, 6,--trioxaspiro(4,4) nonane (MMTN) with acrylonitrile (AN), methyl acrylate (MA) was fol-lowed by high pressure liquid chromatography. The monomer reactivity ratioes werecalculated with the method of i

       

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