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    段先泉 徐纪刚 何北海 李军荣 孙玉山, 徐纪刚, 何北海, 李军荣, 孙玉山. 壳聚糖在1-乙基-3-甲基咪唑醋酸盐溶液中的流变行为[J]. 功能高分子学报, 2011, 24(4).
    引用本文: 段先泉 徐纪刚 何北海 李军荣 孙玉山, 徐纪刚, 何北海, 李军荣, 孙玉山. 壳聚糖在1-乙基-3-甲基咪唑醋酸盐溶液中的流变行为[J]. 功能高分子学报, 2011, 24(4).
    DUAN Xianquan1a,2, XU Ji-gang2, HE Bei-hai, LI Jun-rong, SUN Yu-shan. Rheology of Chitosan Solutions in 1-Ethyl-3-Methylimidazolium Acetate[J]. Journal of Functional Polymers, 2011, 24(4).
    Citation: DUAN Xianquan1a,2, XU Ji-gang2, HE Bei-hai, LI Jun-rong, SUN Yu-shan. Rheology of Chitosan Solutions in 1-Ethyl-3-Methylimidazolium Acetate[J]. Journal of Functional Polymers, 2011, 24(4).

    壳聚糖在1-乙基-3-甲基咪唑醋酸盐溶液中的流变行为

    Rheology of Chitosan Solutions in 1-Ethyl-3-Methylimidazolium Acetate

    • 摘要: 离子液体1-乙基-3-甲基咪唑醋酸盐([EMIM]Ac)对壳聚糖具有良好的溶解能力。利用新一代旋转流变仪哈克MARSⅢ考察了壳聚糖[EMIM]Ac溶液的稳态流变和动态流变性能。稳态流变结果表明:当低黏均分子量壳聚糖离子液体溶液的质量分数在3%以下时,溶液呈牛顿性流体特征,高于此质量分数时溶液呈假塑性流体特征;壳聚糖离子液体溶液的黏度、结构黏度指数随着温度升高而降低;在同一质量分数下,溶液黏度随壳聚糖黏均分子量的增大而增加,溶液的恒剪切活化能黏流活化能随着剪切速率的增大而降低。动态流变结果表明:溶液的储能模量和损耗模量随着温度的升高而下降,储能模量与损耗模量存在一个交叉点,该交叉点随着温度升高向高频区移动。

       

      Abstract: The ionic liquid of 1-ethyl-3-methylimidazolium acetate [EMIM]Ac is a good solvent for chitosan. Static and dynamic rheological properties of chitosan[EMIM]Ac solutions were investigated by a Hake MARSⅢ rotational rheometer. Results of static rheological properties show that the low molecular weight chitosan[EMIM]Ac solution is Newtonian flow fluid when the mass fraction is less than 3%, otherwise, it becomes pseudoplastic liquid. The shear viscosity and structural viscosity index decrease with the increasing of temperature. The viscosity of solution increases with the increasing of molecular mass of chitosan at the same concentration. The viscous activation energy at constant shear rate decrease with the increasing of shear rate. The results of dynamic rheological properties show that the storage modulus and loss modulus of the solution decrease with the increasing of temperature. There is a crossing point between the loss modulus curve and storage curve, and it moves to the high frequency area as the temperature increases.

       

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