钴卟啉络合物的氧结合性能及其在功能材料中的应用
Oxygen-binding Properties of Cobaltporphyrins and their Applications in Functional Materials
-
摘要: 钴卟啉可与氧发生迅速、可逆的结合反应,是有效的氧载体,已被用于氧气吸收、光学传感器和氧气选择性分离膜。综述了钴卟啉的立体结构、配住体、环境等对其与氧可逆结合性能的影响,以及钴卟啉在功能材料中的应用。Abstract: Cobaltporphyrins displayed rapid and reversible oxygen-binding properties, and they can be used as efficient oxygen carriers in oxygen absorbents, optical oxygen sensors and oxygen permselective membranes. The effect of spatial structures, ligands and env