酯交换反应对PBT/PC共混体系相容性及热行为的影响
Esterification Reaction Between PBT and PC and Its Effect on the Misbility and Thermal Behavior of PBT/PC Blends
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摘要: 研究了PBT、PC间的酯交换反应及共混体系的相容性和热行为。IR结果表明,在熔融共混过程中PBT、PC间发生了酯交换反应,磷酸三苯酯可在一定程度上抑制酯交换反应的进行,但是当温度过高或共混时间过长时,TPP的作用减弱甚至消失。Abstract: In this paper, the esterification reaction between PBT and PC and its effect on the compatibility and thermal behavior of PBT/PC blends were investigated by using IR, DSC and TGA. The results indicated that the esterification between PBT and PC occurred d