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    汪长春, 府寿宽. 活性自由基聚合法制备以C60封端的聚苯乙烯[J]. 功能高分子学报, 2000, 13(2): 125-128.
    引用本文: 汪长春, 府寿宽. 活性自由基聚合法制备以C60封端的聚苯乙烯[J]. 功能高分子学报, 2000, 13(2): 125-128.
    shu
    WANG Chang-chun, FU Shou-kuan. Preparation of C60-end-Capped Polystyrene with Living Free Radical Polymerization[J]. Journal of Functional Polymers, 2000, 13(2): 125-128.
    Citation: WANG Chang-chun, FU Shou-kuan. Preparation of C60-end-Capped Polystyrene with Living Free Radical Polymerization[J]. Journal of Functional Polymers, 2000, 13(2): 125-128.
    shu

    活性自由基聚合法制备以C60封端的聚苯乙烯

    Preparation of C60-end-Capped Polystyrene with Living Free Radical Polymerization

      摘要
    • 摘要: 通过活性自由基聚合的方法制备了以２，２，６，６－四甲基－４－羟基呱啶氮氧自由基（ＴＥＭＰＯＬ）封端的聚苯乙烯大分子，实验结果证明该反应体系是一个典型的活性自由基聚合体系，同时研究了ＴＥＭＰＯＬ／ＡＩＢＮ的比例及ＡＩＢＮ的含量对聚合反应的影响。用以ＴＥＭＰＯＬ封端的聚苯乙烯和Ｃ６０反应，制得了Ｃ６０的聚苯乙烯高分子衍生物，紫外和ＧＰＣ结果均证明Ｃ６０已连接到聚苯乙烯的长链上，ＧＰＣ的结果还证明，Ｃ６

       

      Abstract: A series of TEMPOL(2,2,6,6-tetramethyl-4-hydropiperdine-1-oxyl)-end-capped polystyrene were prepared with controlled living free radical polymerization. The influences of TEMPOL/AIBN ratio and the AIBN content on the polymerization were also studied, the

       

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