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    哈丽丹·买买提, 阿布力米提, 库尔班江·肉孜, 阿里木江. 甲基丙烯酸丁酯接枝纤维素的制备[J]. 功能高分子学报, 2010, 23(4): 374-379.
    引用本文: 哈丽丹·买买提, 阿布力米提, 库尔班江·肉孜, 阿里木江. 甲基丙烯酸丁酯接枝纤维素的制备[J]. 功能高分子学报, 2010, 23(4): 374-379.
    MAMAT Halidan, Ablimit, ROUZI Kurbanjian, Alimjan. Synthesis of Poly(BMA-Grafted-Cellulose) Copolymer[J]. Journal of Functional Polymers, 2010, 23(4): 374-379.
    Citation: MAMAT Halidan, Ablimit, ROUZI Kurbanjian, Alimjan. Synthesis of Poly(BMA-Grafted-Cellulose) Copolymer[J]. Journal of Functional Polymers, 2010, 23(4): 374-379.

    甲基丙烯酸丁酯接枝纤维素的制备

    Synthesis of Poly(BMA-Grafted-Cellulose) Copolymer

    • 摘要: 为开发纤维素基吸油材料,以棉浆粕为基材、甲基丙烯酸丁酯(BMA)为单体、乙二醇二甲基丙烯酸酯为交联剂,采用悬浮接枝聚合法合成了BMA接枝纤维素的聚合物。采用红外光谱(FT-IR)、X射线衍射(XRD)、扫描电镜(SEM)、热重(TG)、差热(DSC)等手段对所得吸油材料结构进行了表征。考察了引发剂的种类及用量、接枝单体及交联剂用量、反应温度、反应时间等因素对BMA接枝纤维素聚合物的接枝聚合反应性能及吸油性能的影响。结果表明:当m(棉浆粕)∶m(K2S2O8)∶m(BMA)∶m(乙二醇二甲基丙烯酸酯)=1∶0.025∶1.5∶0.005,75 ℃下恒温反应6 h,合成的BMA接枝纤维素的接枝率最高(36.2%),均聚物含量相对较低(5.8%),且吸油性能优良。

       

      Abstract: The poly(BMA)graftedcellulose copolymer was synthesized with the aim of producing cellulose based oil absorption resins from butyl methacrylate modified cotton pulp(cellulose) by suspension graft copolymerization using glycolpropane diacrylate as crosslinker. The structure of the graft copolymer was characterized by means of FT-IR, XRD, SEM, TG, DSC, etc. The effects of reaction conditions, such as kinds and amounts of initiator, weight ratio of monomer and crosslinker , reaction temperature, reaction time etc,on the graft copolymerization and oil pickup ability of the poly(BMA)graftedcellulose copolymer were examined.The optimized reaction conditions for the synthesis of celluloseBMA graft copolymer were : m(Cotton pulp)∶m(K2S2O8 initiator)∶m (Butyl methacrylate graft monomer)∶m(Glycolpropane diacrylate crosslinker)= 1∶0.025∶1.5∶0.005,75 ℃,and 6 h. Under the above conditions, the graft yield reached 36.2%, homopolymer content was 5.8%, and oil pickup abilities were choiced.

       

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