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    阿布力克木·吾布力达, 木合塔尔·依米提, 希尔艾力·买买提依明, 张建平, 阿依姑丽·麦麦吐逊, 司马义·努尔拉. 3-次甲基（4-丁氧基苯胺）噻吩与吡啶、3-丁基噻吩共聚物的金属配合物催化法合成及性能[J]. 功能高分子学报, 2012, 25(1).
    引用本文: 阿布力克木·吾布力达, 木合塔尔·依米提, 希尔艾力·买买提依明, 张建平, 阿依姑丽·麦麦吐逊, 司马义·努尔拉. 3-次甲基（4-丁氧基苯胺）噻吩与吡啶、3-丁基噻吩共聚物的金属配合物催化法合成及性能[J]. 功能高分子学报, 2012, 25(1).
    shu
    Ablikim OBOLDA, Muhtar YIMIT, Xirali MAMTIMIN, ZHANG Jian-ping, Aygul MAMATTURSUN, Ismayil NURULLA. Synthesis and Characterization of Copolymers of 3-Methyne (4-butoxylaniline) thiophene with Pyridine and 3-Butylthiophene Catalyzed by Metal Complexes[J]. Journal of Functional Polymers, 2012, 25(1).
    Citation: Ablikim OBOLDA, Muhtar YIMIT, Xirali MAMTIMIN, ZHANG Jian-ping, Aygul MAMATTURSUN, Ismayil NURULLA. Synthesis and Characterization of Copolymers of 3-Methyne (4-butoxylaniline) thiophene with Pyridine and 3-Butylthiophene Catalyzed by Metal Complexes[J]. Journal of Functional Polymers, 2012, 25(1).
    shu

    3-次甲基（4-丁氧基苯胺）噻吩与吡啶、3-丁基噻吩共聚物的金属配合物催化法合成及性能

    Synthesis and Characterization of Copolymers of 3-Methyne (4-butoxylaniline) thiophene with Pyridine and 3-Butylthiophene Catalyzed by Metal Complexes

      摘要
    • 摘要: 通过Schiff-base 法合成了侧链含席夫碱的新型噻吩单体2,5-二溴-3-次甲基（4-丁氧基苯胺）噻吩，用Ni（Ⅱ）催化剂［二氯-1,3双（二苯基磷）丙烷基镍（Ⅱ）］合成了新型共轭共聚物聚［3次甲基（4丁氧基苯胺）噻吩共3丁基噻吩］（共聚物Ⅰ）和聚［3次甲基（4丁氧基苯胺）噻吩共吡啶］（共聚物Ⅱ）。采用FTIR、1H\|NMR对2种共聚物的化学结构进行了表征，利用UV-Vis、PL、循环伏安等测试方法对其进行光、电性能测试。结果表明：共聚物在氯仿溶液中发黄绿光，共聚物Ⅰ和共聚物Ⅱ的最大发射峰分别位于540 nm和516 nm，该类共聚物均具有一定的电化学活性。

       

      Abstract: A new Schiffbase monomer, 2,5-dibromo-3-methyne (4-butoxylaniline)thiophene, was synthesized by Schiff-base reaction, and two new copolymers, poly［3-methyne (4-butoxylaniline)thiophene-co-3-butylthiophene］ (copolymerⅠ) and poly［3methyne (4-butoxylaniline)thiophenecopyridine］ (copolymerⅡ), were prepared by using nickel (Ⅱ) complex as catalyzer. The chemical structures of polymers were verified by 1H-NMR and FT-IR. Electrical and optical properties were characterized by UV-Vis, PL and cyclic voltammogram. Results show that solutions of copolymerⅠand copolymerⅡemit yellowgreen light in chloroform, with maximum PL emission at 540 nm and 516 nm, respectively. Moreover, the copolymers have certain electrochemical activity.

       

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