金属—卟啉络合体系引发的活性聚合及不死聚合
Living and Immortal Polymerizations Initiated with Metalloporphyrin Complex System
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摘要: 金属-卟啉络合物是一类可以引发环氧化物、环硫化物、内酯、丙烯酸酯及α-甲基丙烯酸酯等进行活性聚合或不死聚合的新型引发剂。本文概述了上述两种聚合反应的机理、特点、在高分子合成中的应用及其与其他活性聚合的区别。Abstract: Metalloporphyrin is a novel initiator system which can initiate the cpoxide, episulfide, lactone, alkyl methacrylate and alkyl acrylate to proceed living and immortal polymerizations. This paper presents a brief review about the two kinds of polymerizatio