电活性大单体的合成
Synthesis of Electroactive Macromonomer and Copolymers
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摘要: 利用氧化偶联反应,由对苯二胺与端胺基被保护的苯胺二聚体,合成了包含苯胺五聚体的电活性大单体,这条合成路线的特点是,保护了苯胺二聚体的胺端基,防止其进一步反应。利用缩聚反应,由已二胺和1,1,2-十二二胺与大单体合成了电活性聚合物。Abstract: Electroactive macromonomer a was synthesized by the oxidative coupling reaction of p-phenylene-diamine and b. This synthetic route protected the amine terminal group of N-phenyl-1,4-phenylenediamine from further reactions. Electroactive copolymers was syn