高级检索

    章林溪, 马海珠. 聚二甲基硅氧烷链的均方迥转半径[J]. 功能高分子学报, 1995, 8(1).
    引用本文: 章林溪, 马海珠. 聚二甲基硅氧烷链的均方迥转半径[J]. 功能高分子学报, 1995, 8(1).
    shu
    Zhang Linxi, Ma Haizhu. Mean-Square Radius of Gyration of Polydimethylsiloxane Chain[J]. Journal of Functional Polymers, 1995, 8(1).
    Citation: Zhang Linxi, Ma Haizhu. Mean-Square Radius of Gyration of Polydimethylsiloxane Chain[J]. Journal of Functional Polymers, 1995, 8(1).
    shu

    聚二甲基硅氧烷链的均方迥转半径

    Mean-Square Radius of Gyration of Polydimethylsiloxane Chain

      摘要
    • 摘要: 采用旋转异构态模型，用ＭｏｎｔｅＣａｒｌｏ方法计算了聚二甲基硅氧烷（Ｐｏｌｙｄｉｍｅｔｈｙｌｓｉｌｏｘａｎｅ）链考虑侧基（ＣＨ３）的均方通转半径。其结果为＜Ｓ２＞／Ｍ＝７．８５×１０－２：（ｇ·ｍｏｌ）与实验结果（７．７×０．３）×１０－２（ｇ·ｍｏｌ）符合得很好。这种方法可进一步研究高分子链的构象性质。

       

      Abstract: The mean-square radius of gyration of polydimethylsiloxane chains, considering the effect of side group, is investigated by using Monte Carlo simulation and the rotational isomeric state model. It is found that it may be written byin agreement with exper

       

      • HTML全文
      • 参考文献(0)
      • 相关文章
      • 施引文献
    • 资源附件(0)

    /

    返回文章
    返回