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    刘新华, 储兆洋, 李永, 杨旭. 基于植酸改性的羽毛吸附材料的制备及其性能[J]. 功能高分子学报, 2017, 30(3): 354-359. doi: 10.14133/j.cnki.1008-9357.2017.03.015
    引用本文: 刘新华, 储兆洋, 李永, 杨旭. 基于植酸改性的羽毛吸附材料的制备及其性能[J]. 功能高分子学报, 2017, 30(3): 354-359. doi: 10.14133/j.cnki.1008-9357.2017.03.015
    LIU Xin-hua, CHU Zhao-yang, LI Yong, YANG Xu. Preparation and Properties of Feather Adsorbent Material Based on Phytic Acid Modification[J]. Journal of Functional Polymers, 2017, 30(3): 354-359. doi: 10.14133/j.cnki.1008-9357.2017.03.015
    Citation: LIU Xin-hua, CHU Zhao-yang, LI Yong, YANG Xu. Preparation and Properties of Feather Adsorbent Material Based on Phytic Acid Modification[J]. Journal of Functional Polymers, 2017, 30(3): 354-359. doi: 10.14133/j.cnki.1008-9357.2017.03.015

    基于植酸改性的羽毛吸附材料的制备及其性能

    Preparation and Properties of Feather Adsorbent Material Based on Phytic Acid Modification

    • 摘要: 以含环氧基的羽毛接枝共聚物(Feather-g-PGMA)为原料、植酸(PA)为改性剂,利用环氧基的开环反应,将PA中的磷酸根基团引入到Feather-g-PGMA表面,制得含有高密度磷酸根的羽毛吸附材料。采用红外光谱(FT-IR)、热重分析(TG)和X衍射图谱(XRD)对改性前后的羽毛进行表征。重点研究了羽毛吸附材料的制备过程及其吸附量的主要影响因素。结果表明:PA成功改性了Feather-g-PGMA。当PA体积分数为25%、温度为70 ℃、时间为4 h时,改性条件最佳。制备的羽毛吸附材料与Pb2+之间可产生配位作用,对Pb2+有强吸附力,吸附容量可达54.4 mg/g。与羽毛相比,热稳定性下降;与Feather-g-PGMA相比,热稳定性增强。

       

      Abstract: Using feather graft copolymers containing epoxy groups (Feather-g-PGMA) as raw material, phytic acid (PA) as modified reagents, the feather adsorbent material with high density phosphate was obtained by the ring-opening reaction of epoxy groups. The modified feather were characterized by Fourier Transform Infrared spectroscopy (FT-IR), Thermogravimetric analysis (TG) and X-ray diffraction (XRD). The preparation process of feather adsorbent material was studied and the effects of concentration, temperature and time on the phytic acid modified Feather-g-PGMA were discussed. Results show that the Feather-g-PGMA can be successfully modified by PA. When the volume fraction of PA is 25%, temperature is 70 ℃ and time is 4 h, the best conditions for modification are obtained. There is a strong coordination bond between Pb2+ and feather adsorbent material, leading to a strong adsorption ability of feather adsorbent material for Pb2+ at 54.4 mg/g. Compared with feather, the thermal stability of feather adsorbent material is decreased. Compared with Feather-g-PGMA, the thermal stability is enhanced.

       

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